Dr. Daniel Higgins

Daniel Higgins

Professor

location King 309 phone 785-532-6371
email higgins@ksu.edu
Research Themes
Functional Materials, Catalysis, and Nanochemistryblank spacerEnergy, Environment, Agriculture, and Sustainabilityblank spacerSpectroscopy, Imaging, and Dynamics
Lab Website Link 785-532-6668 (fax)

Biography

2006-Present
2016-2022
2001-2006
1996-2001
1993-1996
1988-1993
1983-1988
Professor
Professor and Department Head
Associate Professor
Assistant Professor
Postdoctoral Researcher, University of Minnesota
Ph.D. in Analytical Chemistry, University of Wisconsin-Madison
B.A. in Chemistry, St. Olaf College

Research Overview

Research projects in the Higgins labs are centered around the use of novel existing and emerging optical microscopic methods to probe the structure and dynamics of mesostructured materials. Single molecule detection and spectroscopy, along with fluorescence correlation spectroscopy are the most extensively used methods in the group, but we also make use of Raman microscopy and multiphoton-excited fluorescence microscopy as necessary. We are currently investigating the structure and organization of lyotropic liquid crystal mesophases; the structure, organization and mass transport characteristics of mesoporous silica materials and the nanoscale properties of organically-modified silica thin film gradients. We also have projects investigating the electric-field-induced dynamics of DNA at electrode surfaces and are interested in understanding the blinking dynamics of CdSe nanorods dispersed in semiconducting organic polymer films.

Selected publications

  1. Hamid Rashidi, Omid Shafiee, and Daniel A. Higgins. Fluorescence Correlation Spectroscopy Studies of Dye Diffusion on Fresh and Aged Polyethylene Terephthalate. Anal. Chem., 2023, 95, 11849.
  2. Omid Shafiee, Samantha G. Jenkins, Takashi Ito, and Daniel A. Higgins. Diffusion of Hydrophilic to Hydrophobic Forms of Nile red in Aqueous C12EO10 Gels by Variable Area Fluorescence Correlation Spectroscopy. Phys. Chem. Chem. Phys., 2023, 25, 2853.
  3. Hamid Rashidi, Kampbell J. Howard, Takashi Ito, and Daniel A. Higgins. Random Walks and Sticky Surfaces: Single Molecule Measurements of Solute Diffusion in Ethanol/Water-Filled Anodic Alumina Nanopores. J. Phys. Chem. C, 2023, 127, 411.
  4. Abdulhafiz Usman, Shelby L. Weatherbee, Maryanne M. Collinson, Keith L. Hohn, and Daniel A. Higgins. Single Molecule Spectroscopy Studies of Acid-Base Chemical Gradients using Nile Red as a Probe of Local Surface Acidity. Langmuir 2021, 37, 12138.
  5. Judith Bautista-Gomez, Abdulhafiz Usman, Man Zhang, Ryan J. Rafferty, Stefan H. Bossmann, Keith L. Hohn, and Daniel A. Higgins. Fluorescence Spectroscopy Studies of Crossed Aldol Reactions: A Reactive Nile Red Dye Reveals Catalyst-Dependent Product Formation. Catal. Sci. Technol. , 2020, 10, 5579.